Kubiak Research Group

Department of Chemistry & Biochemistry

Research Interests | Publications

Chem Soc Rev

• Guidelines
• Illustrations
• Chem Soc Rev - Endnote Style

Review of Electrocatalysts

• DuBois
  • 2006 - Organometallics
    Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex
  • 2000 - APPLIED ORGANOMETALLIC CHEMISTRY
    Hydricity of transition-metal hydrides and its role in CO2 reduction
  • 1997 - Comments on Inorganic Chemistry
    Development of Transition Metal Phosphine Complexes as Electrocatalysts for CO, and CO Reduction
  • 1997 - Organometallics
    Synthesis and Characterization of Palladium and Nickel Complexes with Positively Charged Triphosphine Ligands and Their Use as Electrochemical CO2-Reduction Catalysts
  • 1995 - Organometallics
    Electrochemical Reduction of CO2 Catalyzed by a Dinuclear Palladium Complex Containing a Bridging Hexaphosphine Ligand: Evidence for Cooperativity
  • 1994 - Organometallics
    Synthesis and Characterization of Palladium Complexes Containing Tridentate Ligands with PXP (X = C, N, 0, S, As) Donor Sets and Their Evaluation as Electrochemical CO2 Reduction Catalysts
  • 1994 - Organometallics
    Exclusion of Six-Coordinate Intermediates in the Electrochemical Reduction of COz Catalyzed by [Pd(triphosphine)(CH&N)] (BF4)2 Complexes
  • 1991 - JACS
    Electrochemical Reduction of C02 Catalyzed by [ Pd( triphosphine)( solvent)]( BF& Complexes: Synthetic and Mechanistic Studies
• Eisenburg
  • 1980 - JACS
    Electrocatalytic Reduction of Carbon Dioxide by Using Macrocycles of Nickel and Cobalt
• Fujita
  • 1991 - JACS
    Carbon Dioxide Activation by Cobalt( I) Macrocycles: Factors Affecting C02 and CO Binding
• Kubiak
  • 2005 - Angewandte
    A Trihydroxy Tin Group That Resists Oligomerization in the Trinuclear Nickel Cluster [Ni3(m-P,P’ PPh2CH2PPh2)3(m3-L)-(m3-Sn(OH)3)]
  • 2005 - Organometallics
    Dinuclear Nickel Complexes as Catalysts for Electrochemical Reduction of Carbon Dioxide
  • 1998 - Chemistry Letters
    Mechanistic and IR Spectrochemical Studies for Alkali Metal Ion Catalyzed Multiple Bond Metathesis Reactions of Carbon Dioxide
  • 1998 - Inorganica Chimica Acta
    Infrared spectroelectrochemical and electrochemical kinetics studies of the reaction of nickel cluster radicals [Ni3(/x2-dppm) 3(/x3-L) (/x3-I) ]'(L = CNR, R =CH3, i-C3H7, C6Hll, CH2C6Hs, t-C4H9, 2,6-Me2C6H3; L =CO) with carbon dioxide
  • 1994 - Inorg. Chem.
    Electrocatalytic Reduction of Carbon Dioxide by the Binuclear Copper Complex [ Cu2(6-(diphenylphosphino)-2,2'-bipyridyl)2(MeCN)2] [PF6]
• Meshitsuka
  • 1974 - J.C.S. CHEM. COMM
    Electrocatalysis by Metal Phthalocyanines in the Reduction of Carbon Dioxide
• Sauvage
  • 1986 - J. Am. Chem. SOC
    Electrocatalytic Reduction of C02 by Ni Cyclam2+ in Water: Study of the Factors Affecting the Efficiency and the Selectivity of the Process
• Saveant
  • 1996 - Faraday
    Mechanism of the electrochemical reduction of carbon dioxide at inert electrodes in media of low proton availability
  • 1996 - JACS
    Homogeneous Electron Transfer Catalysis of the Electrochemical Reduction of Carbon Dioxide. Do Aromatic Anion Radicals React in an Outer-Sphere Manner?
  • 1996 - J Phys Chem
    Catalysis of the Electrochemical Reduction of Carbon Dioxide by Iron(0) Porphyrins. Synergistic Effect of Lewis Acid Cations
• Tanaka
  • 2002 - Coordination Chem Reviews
    Multi-electron reduction of CO2 via Ru-CO2, -C(O)OH, -CO, -CHO, and -CH2OH species
  • 1990 - J Chem Soc Dalton Trans
    Ligand Effects of Ruthenium 2,2'-Bipyridine and 1 ,lo-Phenanthroline Complexes on the Electrochemical Reduction of CO2,
  • 1987 - Organometallics
    Electrochemical COP Reduction Catalyzed by [R~(bpy),(C0),]~+ and [Ru(bpy),(CO)CI]+. The Effect of pH on the Formation of CO and HCOO
• Wagenknecht
  • 1984 - J. Am. Chem. SOC
    Electrochemical Reduction of C02 Catalyzed by Rh( diphos)2Cl

Lessons from Nature - CODH

• Ni-Fe-S
  • 2001 - PNAS
    Life on carbon monoxide: X-ray structure of Rhodospirillum rubrum Ni-Fe-S carbon monoxide dehydrogenase - Catherine L. Drennan*†, Jongyun Heo‡, Michael D. Sintchak*, Eric Schreiter*, and Paul W. Ludden‡
• Mo-Cu
  • 2005 - Inorganic Chemistry
    Sulfido-Bridged Dinuclear Molybdenum-Copper Complexes Related to the Active Site of CO Dehydrogenase: [(dithiolate)Mo(O)S2Cu(SAr)]2- (dithiolate ) 1,2-S2C6H4, 1,2-S2C6H2-3,6-Cl2, 1,2-S2C2H4) - Motoki Takuma, Yasuhiro Ohki, and Kazuyuki Tatsumi*
  • 2002 - PNAS
    Catalysis at a dinuclear [CuSMo(AO)OH] cluster in a CO dehydrogenase resolved at 1.1-Å resolution - Holger Dobbek*†‡, Lothar Gremer†§, Reiner Kiefersauer*¶, Robert Huber*, and Ortwin Meyer‡§
    
  • 1999 - PNAS
    Crystal structure and mechanism of CO dehydrogenase, a molybdo iron-sulfur flavoprotein containing S-selanylcysteine - HOLGER DOBBEK*†, LOTHAR GREMER‡, ORTWIN MEYER‡, AND ROBERT HUBER*

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The Kubiak Laboratory