Clifford P. Kubiak

Selected Publications

Selective Reduction of CO2 to CO by a Molecular Re(ethynyl-bpy)(CO)3Cl Catalyst and Attachment to Carbon Electrode Surfaces. Zhanaidarova, A.; Ostericher A.L.; Miller, C.J.; Jones, S.C.; Kubiak, C.P. Organometallics 2018, Article ASAP.

Direct observation of the intermediate in an ultrafast isomerization. Porter, T.M.; Wang J.; Li, Y.; Xiang, B.; Salsman, C.; Miller, J.S.; Xiong, W.; Kubiak, C.P. Chem. Sci. 2019, 10, 113-117

CO2 Reduction Catalysts on Gold Electrode Surfaces Influenced by Large Electric Fields. Clark, M.L.; Ge, A.; Videla, P.E.; Rudshteyn, B.; Miller, C.J.; Song, J.; Batista, V.S.; Lian, T.; Kubiak, C.P. J. Am. Chem. Soc. 2018, 140, 17643-17655.

Stable Mixed-Valent Complexes Fromed by Electron Delocalization Across Hydrogen Bonds of Pyrimidinone-Linked Metal Clusters. Porter, T.M.; Heim, G.P.; Kubiak, C.P. J. Am. Chem. Soc. 2018, 140, 12756-12759.

Utilization of Thermodynamic Scaling Relationships in Hydricity To Develop Nickel Hydrogen Evolution Reaction Electrocatalysts with Weak Acids and Low Overpotentials. Ostericher, A.L.; Waldie, K.M.; Kubiak, C.P. ACS Catal. 2018, 8, 9596-9603.

Covalent attachment of [Ni(alkynyl-cyclam)]2+ catalysts to glassy carbon electrodes. Zhanaidarova, A.; Moore, C.E.; Gembicky, M.; Kubiak, C.P. Chem. Comm. 2018, 54, 4116-4119.

Transition Metal Hydride Catalysts for Sustainable Interconversion of CO2 and Formate: Thermodynamic and Mechanistic Considerations. Waldie, K.M.; Brunner, F.M.; Kubiak, C.P. ACS Stustainable Chem. Eng. 2018, 6, 6841-6848.

Symmetry-Breaking Charge Transfer in Boron Dipyridylmethene (DIPYR) Dimers.Golden, J.H.; Estergreen, L.; Porter, T.P.; Tadle, A.C.; Sylvinson M. R., D.; Facendola, J.W.; Kubiak, C.P.; Bradforth, S.E.; Thompson, M.E. ACS Appl. Energy Mater. 2018, 1, 1083-1095.

Kinetic and Mechanistic Effects of Bipyridine (bpy) Substituent, Labile Ligand, and Brønsted Acid on Electrocatalytic CO2 Reduction by Re(bpy) Complexes. Clark, M.L.; Cheung, P.L.; Lessio, M.; Carter, E.A.; Kubiak, C.P. ACS Catal. 2018, 8, 2021-2029.

Synthesis and Characterization of Heteroleptic Ni(II) Bipyridine Complexes Bearing Bis(N-heterocyclic carbene) Ligands. Reineke M.H.; Porter, T.M. Ostericher, A.L.; Kubiak, C.P. Organometallics. 2018, 37(3), 448-453.

Hydricity of transition metal hydrides: thermodynamic considerations for CO2 reduction. Waldie, K.M.; Ostericher, A.L.; Reineke, M.; Sasayama, A.F.; Kubiak, C.P. ACS Catal. 2018, 8, 1313-1324.

Effects of Electron Transfer on the Stability of Hydrogen Bonds. Porter, T.M.; Heim, G.P.; Kubiak, C.P. Chem. Sci. 2017, 8, 7324-7329.

Chelated [Zn(cyclam)]2+ Lewis Acid Improves the Reactivity of the Electrochemical Reduction of CO2 by Mn Catalysts with Bulky Bipyridine Ligands. Zhanaidarova, A.; Steger, H.; Reineke, M.H.; Kubiak, C.P. Dalton Trans. 2017, 46, 12413-12416.

Interfacial Structure and Electric Field Probed by in Situ Electrochemical Vibrational Stark Effect Spectroscopy and Computational Modeling Ge, A.; Videla, P.E.; Lee, G.L.; Rudshteyn, B.; Song, J.; Kubiak, C.P.; Batista, V.S.; Lian, T. J. Phys. Chem. C 2017, 121, 18674–18682.

Electrode-Ligand Interactions Dramatically Enhance CO2 Conversion to CO by the [Ni(cyclam)](PF6)2 Catalyst Wu, Y.; Rudshteyn, B.; Zhanaidarova, A.; Froehlich, J.D.; Ding, W.; Kubiak, C.P.; Batista, V.S. ACS Catal. 2017, 7, 5282-5288.

Concerted One-Electron Two-Proton Transfer Processes in Models Inspired by the Tyr-His Couple of Photosystem II Huynh, M.T.; Mora, S.J.; Villalba, M.; Tejeda-Ferrari, M.E.; Liddell, P.A.; Cherry, B.R.; Teillout, A.-L.; Machan, C.W.; Kubiak, C.P.; Gust, D.; Moore, T.A.; Hammes-Schiffer, S.; Moore, A.L. ACS. Cent. Sci. 2017, 3 (5), 372-380.

Charged Macromolecular Rhenium Bipyridine Catalysts with Tunable CO2 Reduction Potentials Sahu, S.; Cheung, P.L.; Machan, C.W.; Chabolla, S.A.; Kubiak, C.P.; Gianneschi, N.C. Chem. Eur. J. 2017, 23 (36), 8619-8622.

Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups Chabolla, S.A.; Machan, C.W.; Yin, J.; Dellamary, E.A.; Sahu, S.; Gianneschi, N.C.; Gilson, M.K.; Tezcan, F. A.; Kubiak, C.P. Faraday Discuss. 2017, 198, 279-300.

Hydrophobic Nanoparticles Reduce the β-sheet content of SEVI Amyloid Fibrils and Inhibit SEVI-Enhanced HIV Infectivity Sheik, D.A.; Chamberlain, J.M.; Brooks, L.R.; Clark, M.L.; Kim, Y. H.; Leriche, G.; Kubiak, C.P.; Dewhurst, S.; Yang, J. Langmuir, 2017, 33 (10), 2595-2602.

Electrochemical Properties and CO2-Reduction Ability of m-Terphenyl Isocyanide Supported Manganese Tricarbonyl Complexes Agnew, D.W.; Sampson, M.D.; Moore, C.E.; Rheingold, A.L.; Kubiak, C.P.; Figueroa, J.S. Inorg. Chem. 2016, 55 (23), 12400-12408.

Paired Electrolysis in the Simultaneous Production of Synthetic Intermediates and Substrates Llorente, M.J.; Nguyen, B.H.; Kubiak, C.P.; Moeller, K.D. J. Am. Chem. Soc. 2016, 138 (46), 15110-15113.

Electrocatalytic reduction of carbon dioxide with Mn(terpyridine) carbonyl complexes Machan, C.W.; Kubiak, C.P. Dalton Trans., 2016, 45, 17179-17186.

Tuning Electron Delocalization and Transfer Rates in Mixed-Valent Ru3O Complexes Through ‘Push-Pull’ Effects Porter, T.M.; Canzi, G.C.; Chabolla, S.A.; Kubiak, C.P. J. Phys. Chem. A, 2016, 120 (32), 6309-6316.

Interrogating heterobimetallic co-catalytic responses for the electrocatalytic reduction of CO2 using supramolecular assembly Machan, C.W.; Kubiak, C.P. Dalton Trans. 2016, 45, 15942-15950.

A Series of Diamagnetic Pyridine Monoimine Rhenium Complexes with Different Degrees of Metal-to-Ligand Charge Transfer: Correlating 13C NMR Chemical Shifts with Bond Lengths in Redox-Active Ligands. Sieh, D.; Kubiak, C.P. Chem. Eur. J. 2016, 22 (30). 10638-10650.

Improving the Efficiency and Activity of Electrocatalysts for the Reduction of CO2 Through Supramolecular Assembly with Amino Acid-Modified Ligands. Machan, C.W.; Yin, J.; Chabolla, S.A.; Gilson, M.K.; Kubiak, C.P. J. Am. Chem. Soc. 2016, 138 (26), 8184-8193.

Re(I) NHC Complexes for Electrocatalytic Conversion of CO2. Stanton, C.J.; Machan, C.W.; Vandezande, J.E.; Jin, T.; Majetich, G.F.; Schaefer, H.F.; Kubiak, C.P.; Li, G.; Agarwal, J. Inorg. Chem. 2016, 55 (6), 3136-3144.

Rapid synthesis of redox-active dodecaborane B12(OR)12 clusters under ambient conditions. Wixtrom, A.I.; Shao, Y.; Jung, D.; Machan, C.W.; Kevork, S.N.; Qian, E.A.; Axtell, J.C.; Khan, S.I.; Kubiak, C.P.; Spokoyny, A.M. Inorg. Chem. Front. 2016, 3. 711-717.

Characterizing interstate vibrational coherent dynamics of surface adsorbed catalysts by fourth-order 3D SFG spectroscopy. Li, Y.; Wang, J.; Clark, M.L.; Kubiak, C.P.; Xiong, W. Chem. Phys. Lett. 2016, 650, 1-6.

Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3. Cheung, P.L.; Machan, C.W.; Malkhasian, A.Y.; Agarwal, J.; Kubiak, C.P. Inorg. Chem. 2016, 55 (6), 3192-3198.

Nitrite reduction on a multimetallic porphyrin/polyoxotungstate layer-by-layer modified electrodes. Garcia, M.; Honores, J.; Quezada, D.; Diaz, C.; Dreyse, P.; Celis, F.; Kubiak, C.P.; Canzi, G.; Guzman, F.; Aguirre, M.J.; Isaacs, M. Electrochim. Acta, 2016, 192, 61-71.

Electronic effects on the catalytic disproportionation of formic acid to methanol by [Cp*IrIII(R-bpy)Cl]Cl complexes. Sasayama, A.F.; Moore, C.E.; Kubiak, C.P. Dalton Trans. 2016, 45, 2436-2439.

Manganese Electrocatalysts with Bulky Bipyridine Ligands: Utilizing Lewis Acids to Promote Carbon Dioxide Reduction at Low Overpotentials. Sampson, M.D.; Kubiak, C.P. J. Am. Chem. Soc. 2016, 138 (4), 1386-1393.

Competing Ferro- and Antiferromagnetic Interactions in a Hexagonal Bipyramidal Nickel Thiolate Cluster. Hamaguchi, T.; Doud, M.D.; Hilgar, J.; Rinehart, J.D.; Kubiak, C.P. Dalton Trans. 2016, 45, 2374-2377.

Orientation of Cyano-Substituted Bipyridine Re(I) fac-Tricarbonyl Electrocatalysts Bound to Conducting Au Surfaces. Clark, M.L.; Rudshteyn, B.; Ge, A.; Chabolla, S.A.; Machan, C.W.; Psciuk, B.T.; Song, J.; Canzi, G.; Lian, T.; Batista, V.S.; Kubiak, C.P. J. Phys. Chem. C. 2016, 120 (3), 1657-1665.

Short-range catalyst-surface interactions revealed by heterodyne two-dimensional sum frequency generation. Wang, J.; Clark, M.L.; Li, Y.; Kaslan, C.L.; Kubiak, C.P.; Xiong, W. J. Phys. Chem. Lett. 2015, 6, 4204-4209.

Fe-Porphyrin Based MOF Films as High-Surface-Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO2 Hod, I.; Sampson, M.D.; Deria, P; Kubiak, C.P.; Farha, O.K.; Hupp, J.T. ACS Catal. 2015, 5, 6302-6309.

A porous proton-relaying metal-organic framework material that accelerates electrochemical hydrogen evolution Hod, I.; Deria, P.; Bury, W.; Mondloch, J.E.; Kung, C-W.; So, M.; Sampson, M.D.; Peters, A.W.; Kubiak, C.P.; Farha, O.K.; Hupp, J.T. Nature Commun. 2015, 6, 8304.

Electrocatalytic Reduction of Carbon Dioxide by Mn(CN)(2,2′-bipyridine)(CO)3: CN Coordination Alters Mechanism Machan, C.W.; Stanton III, C.J.; Vandazande, J.E.; Majetich, G.F.; Schaefer, H.F.; Kubiak, C.P.; Agarwal, J. Inorg. Chem., 2015, 54(17), 8849-8856.

Reductive Disproportionation of Carbon Dioxide by an Alkyl-Functionalized Pyridine Monoimine Re(I) fac-Tricarbonyl Electrocatalyst Machan, C.W.; Chabolla, S.A.; Kubiak, C.P. Organometallics, 2015, 34(19) 4678-4683.

Electron Dynamics and IR Peak Coalescence in Bridged Mixed Valence Dimers Studied by Ultrafast 2D-IR Spectroscopy Zoerb, M.C.; Henderson, J.S.; Glover, S.D.; Lomont, J.P.; Nguyen, S.C.; Hill, A.D.; Kubiak, C.P.; Harris, C.B. J. Phys. Chem. B, 2015, 119 (33), 10738-10749.

Photocatalytic CO2 Reduction to Formate Using a Mn(I) Molecular Catalyst in a Robust Metal–Organic Framework Fei, H.; Sampson, M.D.; Lee, Y.; Kubiak, C.P.; Cohen, S.M. Inorg. Chem., 2015, 54 (14), 6821-6828.

Electrocatalytic Dihydrogen Production by an Earth-Abundant Manganese Bipyridine Catalyst. Sampson, M.D.; Kubiak, C.P. Inorg. Chem., 2015, 54 (14) 6674-6676.

A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate. Machan, C.W.; Sampson, M.D.; Kubiak, C.P. J. Am. Chem. Soc., 2015, 137 (26) 8564-8571. Correction.

Incorporation of Pendant Bases into Rh(diphosphine)2 Complexes: Synthesis, Thermodynamic Studies, And Catalytic CO2 Hydrogenation Activity of [Rh(P2N2)2]+ Complexes. Lilio, A.M.; Reineke, M.H.; Moore, C.E.; Rheingold, A.L.; Takase, M.K.; Kubiak, C.P. J. Am. Chem. Soc., 2015, 137 (25) 8251-8260.

Reduction of CO2 by Pyridine Monoimine Molybdenum Carbonyl Complexes: Cooperative Metal–Ligand Binding of CO2. Sieh, D.; Lacy, D.C.; Peters, J.C.; Kubiak, C.P.; Chem. Eur. J., 2015, 21 (23), 8497-8503.

Synthesis and Structural Studies of Nickel(0) Tetracarbene Complexes with the Introduction of a New Four-Coordinate Geometric Index, τδ. Reineke, M.H.; Sampson, M.D.; Rheingold, A.L.; Kubiak, C.P.; Inorg. Chem., 2015, 54 (7), 3211-3217.

The Homogeneous Reduction of CO2 by [Ni(cyclam)]+: Increased Catalytic Rates with the Addition of a CO Scavenger. Froehlich, J.D.; Kubiak, C.P.; J. Am. Chem. Soc., 2015, 137 (10), 3565-3573.

Improved PeT Molecules for Optically Sensing Voltage in Neurons. Woodford C.R., Frady, P.E., Smith R.S., Morey B., Canzi G., Palida S.F., Araneda R.C., Kristan, W.B., Jr., Kubiak C.P., Miller E.W., and Tsien, R.Y. J. Am. Chem. Soc., 2015, 137 (5), 1817-1824.

Electron-Transfer Reactions of Electronically Excited Zinc Tetraphenylporphyrin with Multinuclear Ruthenium Complexes. Henderson, J.; Glover, S.D.; Lear, B.J.; Walker, D.; Winkler, J.R.; Gray, H.B.; Kubiak, C.P.; J. Phys. Chem. B, 2015, 119 (24), 7473-7479.

Time-Resolved Electron Transfer in Porphyrin-Coordinated Ruthenium Dimers: From Mixed-Valence Dynamics to Hot Electron Transfer. Petersson, J.; Henderson, J.; Brown, A.; Hammarstrom, L.; Kubiak, C.P.; J. Phys. Chem. C, 2015, 119 (9), 4479-4487.

Synthesis, Spectroscopy, and Electrochemistry of (α-Diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction.Vollmer, M.W.; Machan, C.W.; Clark, M.L.; Antholine, W.E.; Agarwal, J.; Schaefer III, H.F.; Kubiak, C.P.; Walensky, J.R. Organometallics, 2015, 34 (1), 3-12.

Mechanistic Contrasts between Manganese and Rhenium Bipyridine Electrocatalysts for the Reduction of Carbon Dioxide. Riplinger, C.; Sampson, M.D.; Ritzmann, A.M.; Kubiak, C.P.; Carter, E.A. J. Am. Chem. Soc., 2014, 136(46) 16285-16298.

Photoinduced Mixed Valency in Zinc Porphyrin Dimer of Triruthenium Cluster Dyads. Henderson, J.; Kubiak, C.P. Inorg. Chem., 2014, 53(20) 11298-11306.

Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential. Machan, C.W.; Chabolla, S.A.; Yin, J.; Gilson, M.K.; Tezcan, F.A.; Kubiak, C.P. J. Am. Chem. Soc., 2014, 136(41) 14598-14607.

Combined steric and electronic effects of positional substitution on dimethyl-bipyridine rhenium(I)tricarbonyl electrocatalysts for the reduction of CO2. Chabolla, S.A.; Dellamary, E.A.; Machan, C.W.; Tezcan, F.A.; Kubiak; C.P.; Inorg. Chim. Acta, 2014, 422(1) 109-113.

Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry. Machan, C.W.; Sampson, M.D.; Chabolla, S.A.; Dang, T.; Kubiak, C.P. Organomet., 2014, 33 (18), 4550-4559.

Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis. Sampson, M.D.; Nguyen, A.D.; Grice, K.A.; Moore, C.E.; Rheingold, A.L.; Kubiak, C.P. J. Am. Chem. Soc., 2014, 136(14), 5460-5471. Correction.

Electrocatalytic CO2 by M(bpy-R)(CO)4 (M = Mo, W; R = H, tBu) complexes. Electrochemical, spectroscopic, and computational studies and comparison with group 7 catalysts. Clark, M.L.; Grice, K.A.; Moore, C.E.; Rheingold, A.L.; Kubiak, C.P. Chem. Sci., 2014, 5, 1894-1900.

On the Observation of Intervalence Charge Transfer Bands in Hydrogen-Bonded Mixed-Valence Complexes. Canzi, G.; Goeltz, J.C.; Henderson, J.S.; Park, R.E.; Maruggi, C.; Kubiak, C.P.; J. Am. Chem. Soc., 2014, 136(5), 1710-1713.

Chapter Five – Recent Studies of Rhenium and Manganese Bipyridine Carbonyl Catalysts for the Electrochemical Reduction of CO2. Grice, K.A.; Kubiak, C.P.; Adv. Inorg. Chem., 2014, 66, 163-188.

Electro and photoelectrochemical reduction of carbon dioxide on multimetallic porphyrins/polyoxotungstate modified electrodes. Garcia, M.; Aguirre, M.J.; Canzi, G.; Kubiak, C.P.; Ohlbaum, M.; Isaacs, M. Electrochim. Acta, 2014, 115, 146-154.

Direct Observation of the Reduction of Carbon Dioxide by Rhenium Bipyridine Catalysts. Sampson, M.D.; Froehlich, J.D.; Smieja, J.M.; Benson, E.E.; Sharp, I.D.; Kubiak, C.P. Energ. Environ. Sci., 2013, 6, 3748-3755.

Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO2 Reduction by fac-Re(bpy)(CO)3Cl. Keith, J.A.; Grice, K.A.; Kubiak, C.P.; Carter, E.A.; J. Am. Chem. Soc., 2013, 135 (42), 15823-15829.

Synthesis, Structural, and Electrocatalytic Reduction Studies of [Pd(P2N2)2]2+ Complexes Seu, C.S.; Ung, D.; Doud, M.D.; Moore, C. E.; Rheingold, A.L.; Kubiak, C.P.; Organomet., 2013, 32 (16), 4556-4563

Carbon Monoxide Release Catalysed by Electron Transfer: Electrochemical and Spectroscopic Investigations of [Re(bpy-R)(CO)4](OTf) Complexes Relevant to CO2 Reduction. Grice, K.A.; Gu, N.X.; Sampson, M.D.; Kubiak, C.P.; Dalton Trans., 2013, 42 (23), 8498-8503

The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO2 Reduction as Revealed by X-ray Absorption Spectroscopy and Computational Quantum Chemistry Benson, E.E.; Sampson, M.D.; Grice, K.A.; Smieja, J.M.; Froehlich, J.D.,; Friebel, D.; Keith, J.A.; Carter, E.A.; Nilsson, A.; Kubiak, C.K; Angew. Chem. Int. Ed., 2013, 52 (18), 4841-4844

Manganese as a Substitute for Rhenium in CO2 Reduction Catalysts: The Importance of Acids Smieja, J.M.; Sampson, M.D.; Grice, K.A.; Benson, E.E.; Froehlich, J.D.; Kubiak, C.P.; Inorg. Chem., 2013, 52 (5), 2484-2491

Structural and spectroscopic studies of reduced [Re(bpy-R)(CO)3]-1 species relevant to CO2 reduction Benson, E.E.; Grice, K.A.; Smieja, J.M.; Kubiak, C.P.; Polyhedron, 2013, 58, 229-234

A Series of Dinuclear Copper Complexes Bridged by Phosphanylbipyridine Ligands: Synthesis, Structural Characterization and Electrochemistry Lilio, A.M.; Grice, K.A.; Kubiak, C.P.; Eur J. Inorg. Chem., 2013, 22-23, 4016-4023

Inorganic Electron Transfer: Sharpening a Fuzzy Border in Mixed Valency and Extending Mixed Valency across Supramolecular Systems Kubiak, C.P.; Inorg. Chem., 2013, 52 (10), 5663-5676

Structural investigations into the deactivation pathway of the CO2 reduction electrocatalyst Re(bpy)(CO)3Cl Benson, E.E.; Kubiak, C.P.; Chem. Commun., 2012, 48, 7374-7376

Kinetic and structural studies, origins of selectivity, and interfacial charge transfer in the artificial photosynthesis of CO Smieja, J.M.; Benson, E.E.; Kumar, B.; Grice, K.A.; Seu, C.S.; Miller, A.J.M.; Mayer, J.M; Kubiak, C.P.; Proc. Nat. Acad. Sci., 2012, 109 (39), 15646-15650

Controlling the Rate of Electron Transfer between a Quantum Dot and a Tri-Ruthenium Molecular Cluster by Tuning the Chemistry of the Interface Morris-Cohen, A.J.; Aruda, K.O.; Rasmussen, A.; Canzi, G.; Seidemann, T.; Kubiak, C.P.; Weiss, E.; Phys. Chem. Chem. Phys., 2012, 14, 13794-13801

Photoelectrochemical Hydrogen Generation by an [FeFe] Hydrogenase Active Site Mimic at p-Type Silicon/Molecular Catalyst Junction Kumar, B.; Beyler, M.; Kubiak, C. P.; Dr. Sascha Ott. Chemistry - A European Journal. , 2012, 18 (5), 1295-1298

Photochemical and Photoelectrochemical Reduction of CO2 Kumar, B.; Llorente, M.; Froehlich, J.; Dang, T.; Sathrum, A.; Kubiak, C. P. Annu. Rev. Phys. Chem., 2012, 63, 541-569

Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode Froehlich, J. D.; Kubiak, C. P. Inorg. Chem. , 2012, 51(7), 3932-3934

Ultrafast Electron Transfer Across a Gold Nanoparticle: A Study of Ancillary Ligand and Solvent Influences Canzi, G.; Kubiak, C. P. J. Phys. Chem. C , 2012, 166 (11), 6560-6566

Formate oxidation via β-deprotonation in [Ni(PR2NR'2)2(CH3CN)]2+ complexes Seu, C.S.; Appel, A.M.; Doud, M.D.; DuBois, D.L.; Kubiak, C. P. Energ. Environ. Sci. , 2012, 5, 6480-6490

Versatile Synthesis of PR2NR'2 Ligands for Molecular Electrocatalysts with Pendant Bases in the Second Coordination Sphere Doud, M.D.; Grice, K.A.; Lilio, A.M.; Seu, C.S.; Kubiak, C. P. Organometallics, 2012, 31 (3), 779-782

Electrocatalytic Oxidation of Formate by [Ni(PR2NR′2)2(CH3CN)]2+ Complexes Galan, BR; Schöffel, J; Linehan, JC; Seu, C; Appel, AM; Roberts, JAS; Helm, ML; Kilgore, UJ; Yang, JY; Dubois, DL; Kubiak, CP J. Am. Chem. Soc., 2011, 133 (32), 12767-12779

Design of a High Throughput 25-Well Parallel Electrolyzer for the Accelerated Discovery of CO2 Reduction Catalysts via a Combinatorial Approach Dang, T; Ramsaran, R; Roy, S; Froehlich, J; Wang, J; Kubiak, CP Electroanalysis, 2011, 23 (10), 2335-2342

Tunable, light-assisted co-generation of CO and H2 from CO2 and H2O by Re(bipy-tbu)(CO)3Cl and p-Si in non-aqueous medium Kumar, B.; Smieja, J.M.; Sasayama, A.F.; Kubiak, C. P. Chem. Comm., 2011, 48, 272-274

Kinetics and Limiting Current Densities of Homogeneous and Heterogeneous Electrocatalysts Sathrum, A. J.; Kubiak, C. P. J. Phys. Chem. Lett., 2011, 2 (18), 2372–2379

Facile Purification of Iodoferrocene Goeltz, J. C.; Kubiak, C. P. Organometallics, 2011, 30 (14), 3908–3910

Mixed-Valence Nanoclusters: Fast Electron Transfer in Mixed-Valence Systems with a Gold Nanoparticle as the Bridge Canzi, G.; Kubiak, C. P. Small, 2011, 7 (14), 1967–1971

Persistence of the three-state description of mixed valency at the localized-to-delocalized transition Glover, S. D.; Kubiak, C. P. J. Am. Chem. Soc., 2011, 133, 8721-8731

Diffusion-Ordered NMR Spectroscopy as a Reliable Alternative to TEM for Determining the Size of Gold Nanoparticles in Organic Solutions Canzi, G.; Mrse, A. A.; Kubiak, C. P. J. Phys. Chem. C, 2011, 115 (16), 7972-7978

Non-innocent ligand reservoirs for reducing or oxidizing equivalents in carbonylrhenium(I) complexes: 1,1’-bis(diphenylphosphino)ferrocene (dppf) and bis-triazinyl-pyridine (BTP) Roy, S. A.; Blane, T. M.; Lilio, A. M.; Kubiak, C. P. Inorg. Chimica Acta, 2011, Article in Press

Basic ruthenium acetate and mixed valence derivatives Goeltz, J. C.; Glover, S. D.; Hauk, J.; Kubiak, C. P. Inorg. Synth., 2011, 35, 156-159

Mixed Valency Across Hydrogen Bonds. Goeltz, J.C.; Kubiak, C.P. J. Am. Chem. Soc. 2010, 132 (49), 17390–17392

Tricarbonylrhenium(I) complexes of highly symmetric hexaazatrinaphthylene ligands (HATN): structural, electrochemical and spectroscopic properties. Roy, S. A.; Kubiak, C.P. Dalton Trans. 2010, 39, 10937-10943

Photoreduction of CO2 on p-Type Silicon Using Re(bipy-But)(CO)3Cl: Photovoltages Exceeding 600 mV for the Selective Reduction of CO2 to CO Kumar, B.; Smieja, J. M.; Kubiak, C.P. J. Phys. Chem. C, 2010, 114 (33), 14220–14223

Re(bipy-tBu)(CO)3Cl – improved catalytic activity for reduction of carbon dioxide. IR-Spectroelectrochemical and mechanistic studies. Smieja, J. M.; Kubiak, C.P. Inorg. Chem. 2010,49, 9283–9289

Electronic Structural Effects in Self-Exchange Reactions Goeltz, J.G; Benson, E. E.; Kubiak, C.P. J. Phys. Chem. B 2010, 114, 14729-14734

Synthesis and Characterization of 6,6′-(2,4,6-Triisopropylphenyl)-2,2′-bipyridine (tripbipy) and Its Complexes of the Late First Row Transition Metals Benson, E. E.; Rheingold, A. R.; Kubiak, C.P. Inorg. Chem. 2010, 49, 1458-1464

Inter- or intramolecular electron transfer between triruthenium clusters: we’ll cross that bridge when we come to it Glover, S. D.; Goeltz, J.C.; Lear, B. J.; Kubiak, C.P. Coord. Chem. Rev., 2010, 254, 331-345

Rates of Electron Self-Exchange Reactions between Oxo-Centered Ruthenium Clusters Are Determined by Orbital Overlap Goeltz, J. C.; Hanson, C. J.; Kubiak, C. P. Inorg. Chem., 2009, 48, 4763–4767

Mixed Valency at the Nearly Delocalized Limit: Fundamentals and Forecast. Glover, S. D.; Goeltz, J. C.; Lear, B. J.; Kubiak, C. P. Eur J. Inorg. Chem., 2009, 5, 585-594

Electrocatalytic and homogeneous approaches to conversion of CO2 to liquid fuels. Benson, E. E.; Sathrum, A. J.; Smieja, J. S.; Kubiak, C. P. Chem. Soc. Rev., 2009, 38, 89-99

Mixed valence self-assembled monolayers: electrostatic polarizabilities of the mixed valence states. Goeltz, J. C.; Kubiak, C. P. J. Phys. Chem. C, 2008, 112, 8114-8116.

Electron transfer at the Class II/III borderline of mixed valency: dependence of rates on solvent dynamics and observation of a localized-to-delocalized transitioin in freezing solvents. Glover, S. D.; Lear, B. J.; Salsman, J. C.; Londergan, C. H.; Kubiak, C. P. Phil. Trans. Roy. Soc. A., 2008, 366, 177-185.

Solvent dynamical control of ultrafast ground state electron transfer: Implications for class II-III mixed valency. Lear, B. J.; Glover, S. D.; Salsman, J. C.; Londergan, C. H.; Kubiak, C. P. J. Am. Chem. Soc., 2007, 129, 12772-12779.

Origins of Cooperative Non – Covalent Host – Guest Chemistry in Mixed Valence Complexes. Lear, B. J.; Kubiak, C. P. J. Phys. Chem. B., 2007, 111, 6766-6771.

Charge Gating and Electronic Delocalization over a Dendrimeric Assembly of Trinuclear Ruthenium Clusters. Lear, B. J.; Kubiak, C. P. Inorg. Chem., 2006, 45, 7041-7043.

Observation and dynamics of "mixed-valence isomers" and a thermodynamic estimate of electronic coupling parameters. Londergan, C. H.; Salsman, J. C.; Lear, B. J.; and Kubiak, C. P. Chemical Physics, 2006, 324, 57-62.

Tuning the Electronic Communication and Rates of Intramolecular Electron Transfer of Dimers of Trinuclear Ruthenium Clusters: Bridging and Ancillary Ligand Effects. Salsman, J. C.; Ronco, S.; Londergan, C. H.; and Kubiak, C. P. Inorg. Chem., 2006, 45, 547-554.

Intervalence-Resonant Raman Spectroscopy of Strongly Coupled Mixed-Valence Cluster Dimers of Ruthenium. Rocha, R. C.; Brown, M. G.; Londergan, C. H.; Salsman, J. C.; Kubiak, C. P.; and Shreve, A. P. J. Phys. Chem. A, 2005, 109, 9006-9012.

Infrared spectroscopic determination of the degree of charge transfer in complexes of TCNE with methyl-substituted benzenes. Stires, J. C.; McLaurin, E. J.; and Kubiak, C. P.; Chem. Commun., 2005, 28, 3532-3534.

Mixed valence isomers. Salsman, J. C.; and Kubiak, C. P.; J. Am. Chem. Soc., 2005, 127, 2382-2383.

A trihydroxy tin group that resists oligomerization in the trinuclear nickel cluster [Ni3(μ-P,P'-PPh2CH2PPh2)3(μ3-L)(μ3-Sn(OH)3)]. Simon-Manso, E; and Kubiak, C. P.; Angew. Chem. Int. Ed., 2005, 44, 1125-1128.

An Anionic Zerovalent Nickel Carbonyl Complex Supported by a Triphosphine Borate Ligand: An Ni-C≡O-Li Isocarbonyl. Hou, H. Y.; Rheingold, A. L.; and Kubiak, C. P. Organometallics, 2005, 24, 231-233.

Dinuclear Nickel Complexes as Catalysts for Electrochemical Reduction of Carbon Dioxide. Simon-Manso, E.; and Kubiak, C. P. Organometallics, 2005, 24, 96-102.

Observation and Dynamics of Charge Transfer Isomers. Ito, T; Yamaguchi, T; Imai, N.; Londergan, C. H.; and Kubiak, C. P. Angew. Chem. Int. Ed., 2004, 43, 1376-1381

Structural, Spectroscopic, and Electrochemical Studies of the Complexes [Ni2(μ-CNR)(CNR)2(μ-dppm)2]n+ (n = 0, 1, 2): Unusual Examples of Nickel(0)-Nickel(I) and Nickel(0)-Nickel(II) Mixed Valency. Ferrence, G. M.; Simon-Manso, E.; Breedlove, B. K.; Meeuwenberg, L.; and Kubiak, C. P. Inorg. Chem., 2004, 43, 1071-1081.

Electron transfer and dynamic infrared-band coalescence: It looks like dynamic NMR spectroscopy, but a billion times faster. Londergan, C. H.; and Kubiak, C. P. Chemistry - A European Journal, 2003, 9, 5962-5969.

Intervalence Involvement of Bridging Ligand Vibrations in Hexaruthenium Mixed-Valence Clusters Probed by Resonance Raman Spectroscopy. Londergan, C. H.; Rocha, R. C.; Brown, M. G.; Shreve, A. P.; and Kubiak, C. P. J. Am. Chem. Soc., 2003, 125, 13912-13913.

Vibronic Participation of the Bridging Ligand in Electron Transfer and Delocalization: New Application of a Three-State Model in Pyrazine-Bridged Mixed-Valence Complexes of Trinuclear Ruthenium Clusters. Londergan, C. H.; and Kubiak, C. P. J. Phys. Chem. A, 2003, 107, 9301-9311.

Hydrocarbation Chemistry Proceeding from Nickel Carbenes. Hou, H. Y.; Gantzel, P. K.; and Kubiak, C. P. J. Am. Chem. Soc., 2003, 125, 9564-9565.

Rapid phosphorus-nitrogen bond cleavage in bis(diphenylphosphino)amine. Synthesis, X-ray structure and electrochemical characterization of [Ni2(μ2-Ph2P)(μ2-Ph2PNHPPh)2(CNR)2]X, R=Me, n-Bu, Xylyl; X = Cl, I, BPh4 binuclear Ni(I) complexes. Simon-Manso, E.; and Kubiak, C. P. Inorg. Chem. Commun., 2003, 6, 1096-1098.

Synthesis, molecular structure and electrochemical studies of the bis(diphenylphosphino)amine bridge triangular nickel clusters. Simon-Manso, E.; Gantzel, P.; and Kubiak, C. P. Polyhedron, 2003, 22, 1641-1644.

Efficient Synthesis of N-Aryl Nickel(II) Carbenes by Protonation of Nickel(0) Isocyanide Complexes. Hou, H. Y.; Gantzel, P. K.; and Kubiak, C.P. Organometallics, 2003, 22, 2817-2819.

Infrared Activity of Symmetric Bridging Ligand Modes in Pyrazine-Bridged Hexaruthenium Mixed-Valence Clusters. Londergan, C. H.; Salsman, J. C.; Ronco, S.; and Kubiak, C. P. Inorg. Chem., 2003, 42, 926-928.

Molecular Wire Junctions: Tuning the Conductance. Mujica, V.; Nitzan, A.; Datta, S.; Ratner, M. A.; and Kubiak, C. P. J. Phys. Chem. B, 2003, 107, 91-95.

Reversibly Altering Electronic Conduction Through a Single Molecule by a Chemical Binding Event. Kasibhatla, B.S.T.; Labonte, A.P.; Zahid, F.S.; Reifenberger, R.G.; Datta, S.; and Kubiak, C. P. J. Phys. Chem. B, 2003, 107, 12378-12382.

Electrostatic investigation into the bonding of poly(phenylene) thiols to gold. McNally, H.; Janes, D. B.; Kasibhatla, B.; and Kubiak, C. P. Superlattices and Microstructures, 2002, 31, 239-245.

Inter- and Intramolecular π -Stacking Interactions in cis-Bis{1-(9-anthracene)}phosphirane Complexes of Platinum(II). Yang, F.; Fanwick, P. E.; and Kubiak, C. P. Inorg. Chem., 2002, 41, 4805-4809.

In Search of the Elusive Open-Faced Triangulo Nickel Cluster: Insertion of Thallium(I) into a μ 3-I Capping Ligand. Johnson, M. J. A.; Gantzel, P. K.; and Kubiak, C. P. Organometallics, 2002, 21, 3831-3832.

Tin-Capped Trinuclear Nickel Clusters: Redox Isomerism between μ3-Stannyl and μ3-Stannylene Clusters of the Class [Ni3(dppm)3(μ3-I)(μ3-SnClx)]n+ (x = 2, n = 1; x = 3, n = 0). Breedlove, B. K.; Fanwick, P. E.; and Kubiak, C. P. Inorg. Chem., 2002, 41, 4306-4308.

Molecular Electrostatics of Conjugated Self-Assembled Monolayers on Au(111) Using Electrostatic Force Microscopy. Howell, S.; Kuila, D.; Kasibhatla, B.; Kubiak, C. P.; Janes, D.; Reifenberger, R.; Langmuir, 2002, 18, 5120-5125.

Solvent Dynamical Control of Electron-Transfer Rates in Mixed-Valence Complexes Observed by Infrared Spectral Line Shape Coalescence. Londergan, C. H.; Salsman, J. C.; Ronco, S.; Dolkas, L. M.; and Kubiak, C. P. J. Am. Chem. Soc., 2002, 124, 6236-6237.

Chiral sulfur diphosphazanes derived from (S)-(Ph2P)2N(CHMePh) and their rhodium(I), (III) and iridium(III) complexes. Crystal structures of Ph2P(S)N(CHMePh)PPh2, {Ph2P(S)}2N(CHMePh) and [(Cp*)MCl{η2-P,S-Ph2PNHP(S)Ph2}]BF4, Cp* = η5-C5Me5; M = Rh, Ir. Simon-Manso, E.; Valderrama, M.; Gantzel, P.; and Kubiak, C. P. J. Organomet. Chem., 2002, 651, 90-97.

A Photoelectrochemical Approach to Splitting Carbon Dioxide for a Manned Mission to Mars. Breedlove, B.K.; Ferrence, G.M.; Washington J; Kubiak, C.P. Matt. Design, 2001, 22, 577-584.

A Versatile Variable Temperature Thin Layer Reflectance Spectroelectrochemical Cell. Zavarine, I.S. and Kubiak, C.P. J. Electroanal. Chem., 2001, 495, 106-109

Adsorption of Diisocyanides on Gold. Henderson, J.I.; Feng, S.; Bein, T. and Kubiak, C.P. Langmuir, 2000, 16, 6183-87

Multiple Bond Metatheses Between Carbon Dioxide and the Isocyanide Ligands of Mononuclear Nickel(0) Tetrakis-Isocyanide Complexes: Catalysis by Alkali Metal Ions. Kim, W.Y.; Chang, J.S.; Park, S.E and Kubiak, C.P. Res. Chem. Intermed., 1999, 25, 459-469

Electron Transfer on the Infrared Vibrational Time Scale in the Mixed Valence State of 1,4-Pyrazine- and 4,4'-Bipyridine-Bridged Ruthenium Cluster Complexes. Ito, T.; Hamaguchi, T.; Nagino, H.; Yamaguchi, T.; Kido, H.; Zavarine, I.S.; Richmond, T.; Washington, J. and Kubiak, C.P. J. Am. Chem. Soc., 1999, 121, 4625-4632.

Conductance Spectra of Molecular Wires. Tian, W.; Datta, S.; Hong, S.; Reifenberger, R.G.; Henderson, J.I. and Kubiak, C.P. J. Chem. Phys., 1998, 109, 2874-2882.

Infrared Spectroelectrochemical and Electrochemical Kinetics Studies of the Reaction of Nickel Cluster Radicals [Ni3(µ2-dppm)3(µ3-L)(µ3-I)]o(L = CNR, R = CH3, i-C3H7, C6H11, CH2C6H5, t-C4H9, 2,6-Me2C6H3; L = CO) with Carbon Dioxide. Wittrig, R.E.; Ferrence, G.M.; Washington, J. and Kubiak, C.P. Inorg Chim. Acta., 1998, 270, 111-117

Resistance of Molecular Nanostructures. Tian, W.; Datta, S.; Hong, S.; Reifenberger, R.G.; Henderson, J.I. and Kubiak, C.P. Physica E, 1998, 1, 304-309

STM Current-Voltage Characteristics of Self-Assembled Monolayers (SAM's). Datta, S.; Tian, W.; Hong, S.; Reifenberger, R.G.; Henderson, J.I. and Kubiak, C.P. Phys. Rev. Lett., 1997, 79, 2530-2533

Effects of Rapid Intramolecular Electron Transfer on Vibrational Spectra. Ito, T.; Hamaguchi, T.; Nagino, H.; Yamaguchi, T.; Washington, J. and Kubiak, C.P. Science, 1997, 277, 660-663

Self-Assembly of a Two-Dimensional Superlattice of Molecularly Linked Metal Clusters. Andres, R. P.; Bielefeld, J.D.; Henderson, J.I.; Janes, D.B.; Kolagunta, V.R.; Kubiak, C.P.; Mahoney, W. and Osifchin, R.G. Science, 1996, 273, 1690-1693